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FTIR STUDY OF CO/O(2) REACTION OVER Pt-Rh/Al(2)O(3) CATALYSTS

被引：21
作者：
Anderson, James A. [1 ]
Rochester, Colin H. [1 ]
机构：
[1] Univ Dundee, Dept Chem, Dundee DD1 4HN, Scotland
来源：
CATALYSIS TODAY | 1991年 / 10卷 / 03期
关键词：
Alumina - Chemical Reactions - Spectroscopic Analysis - Oxides - Forming - Salts - Spectroscopy; Infrared;
D O I：
10.1016/0920-5861(91)80007-V
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Infrared spectra are reported for the reaction of CO and 0 over two Pt-Rh/Al(2)O(3) catalysts in the range 300-573 K. The formation of stable platinum (II) carbonyl species for catalyst prepared by stepwise impregnation of alumina by salts of the two metals was not observed for catalysts prepared by a simultaneous impregnation method. Short range platinum-rhodium interactions for the latter may reduce the tendency for oxide formation leading to loss of oxidation activity.
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页码：275 / 282
页数：8
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