Chiral Compounds of Essential Oils. Part XVI. Enantioselective Multidimensional Gas Chromatography in Authenticity Control of Balm Oil (Melissa officinalis L.)

被引:24
作者
Kreis, Peter [1 ]
Mosandl, Armin [1 ]
机构
[1] Univ Frankfurt, Biozentrum, Inst Lebensmittelchem, D-60439 Frankfurt, Germany
关键词
Enantiomeric separation of essential oil compounds Enantioselective multidimensional gas chromatography (enantio-MDGC); cis/trans Rose oxides; Octan-3-ol; Oct-1-en-3-ol; Linalol; Citronellal; Citronellol; Citronellic acid methyl ester; Authenticity assessment of balm oil; Melissa officinalis L;
D O I
10.1002/ffj.2730090510
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Using enantioselective multidimensional gas chromatography (enantio-MDGC) and the column combination polyethylene glycollheptakis (2,3-di-O-acetyl-6-O-tert-butyldimethylsilyl)-beta-cyclodextrin in OV 1701-vi, the chiral monoterpenoids cis/trans-rose oxides, octan-3-ol, oct-1-en-3-ol, linalol, citronellal, citronellol and citronellic acid methyl ester were stereoanalysed. The method is applied to chirality evaluation of these compounds from balm oils. The enantiomeric distributions are discussed in order to assess the authenticity of this essential oil.
引用
收藏
页码:249 / 256
页数:8
相关论文
共 20 条
[1]   INVESTIGATIONS OF THE CONTENT AND COMPOSITION OF ESSENTIAL OIL OF MELISSA-OFFICINALIS .1. GENETIC-VARIABILITY OF THE ESSENTIAL OIL CONTENT OF MELISSA-OFFICINALIS [J].
ADZET, T ;
PONZ, R ;
WOLF, E ;
SCHULTE, E .
PLANTA MEDICA, 1992, 58 (06) :558-561
[2]   INVESTIGATIONS OF THE CONTENT AND COMPOSITION OF ESSENTIAL OIL OF MELISSA-OFFICINALIS .2. CONTENT AND COMPOSITION OF M-OFFICINALIS OIL IN RELATION TO LEAF POSITION AND HARVEST TIME [J].
ADZET, T ;
PONZ, R ;
WOLF, E ;
SCHULTE, E .
PLANTA MEDICA, 1992, 58 (06) :562-564
[3]  
Deger W., 1988, THESIS WURZBURG U
[4]  
Dietrich A., 1992, Journal of High Resolution Chromatography and Chromatography Communications, V15, P176, DOI 10.1002/jhrc.1240150308
[5]  
Gessner M., 1988, THESIS WURZBURG U
[6]  
Gildemeister E., 1961, ATHERISCHEN OLE, V7, P286
[7]  
Grob K., 1986, MAKING MANIPULATING
[8]  
Hartke K., 1988, DAB 9 KOMMENTAR, V3, P2244
[9]  
Konig WA, 1989, J HIGH RES CHROMATOG, V12, P732, DOI DOI 10.1002/JHRC.1240121108
[10]   Chiral Compounds of Essential Oils. Part XII. Authenticity Control of Rose Oils, Using Enantioselective Multidimensional Gas Chromatography [J].
Kreis, Peter ;
Mosandl, Armin .
FLAVOUR AND FRAGRANCE JOURNAL, 1992, 7 (04) :199-203