THE RUTHENIUM CATALYZED ASYMMETRIC HYDROGENATION OF OXIMES USING BINAP AS THE CHIRAL LIGAND

被引：33

作者：

KRASIK, P ^{[1
]}

ALPER, H ^{[1
]}

机构：

[1] UNIV OTTAWA,OTTAWA CARLETON CHEM INST,DEPT CHEM,OTTAWA K1N 6N5,ONTARIO,CANADA

来源：

TETRAHEDRON-ASYMMETRY | 1992年 / 3卷 / 10期

基金：

加拿大自然科学与工程研究理事会;

关键词：

D O I：

10.1016/S0957-4166(00)82086-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The ruthenium BINAP complex, [RuX(arene)[(R)-BINAP]]X, can catalyze the hydrogenation of oximes to amines in moderate enantiomeric excess.

引用

页码：1283 / 1288

页数：6

共 14 条

[1]

BACOS J, 1989, J ORGANOMET CHEM, V370, P263

[2] CATALYTIC ASYMMETRIC HYDROGENATION OF IMINES - USE OF RHODIUM(I)/PHOSPHINE COMPLEXES AND CHARACTERIZATION OF RHODIUM(I)/IMINE COMPLEXES [J].

BECALSKI, AG ;

CULLEN, WR ;

FRYZUK, MD ;

JAMES, BR ;

KANG, GJ ;

RETTIG, SJ .

INORGANIC CHEMISTRY, 1991, 30 (26) :5002-5008

[3]

BOTTEGHI C, 1975, CHIMIA, V29, P256

[4]

CHAN YNC, 1990, J AM CHEM SOC, V112, P9400

[5] CHEMOSELECTIVE HYDROGENATION OF IMINES CATALYZED BY IR(III) COMPLEXES [J].

CHAN, YNC ;

MEYER, D ;

OSBORN, JA .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (12) :869-871

[6] ALPHA-METHOXY-ALPHA-TRIFLUOROMETHYLPHENYLACETIC ACID, A VERSATILE REAGENT FOR DETERMINATION OF ENANTIOMERIC COMPOSITION OF ALCOHOLS AND AMINES [J].

DALE, JA ;

DULL, DL ;

MOSHER, HS .

JOURNAL OF ORGANIC CHEMISTRY, 1969, 34 (09) :2543-&

[7] SOME OBSERVATIONS ON THE RUCL3 PR3 CATALYZED CONVERSION OF PRIMARY AMINES TO SECONDARY-AMINES [J].

JUNG, CW ;

FELLMANN, JD ;

GARROU, PE .

ORGANOMETALLICS, 1983, 2 (08) :1042-1044

[8] RHODIUM(I)-CATALYZED ASYMMETRIC HYDROGENATION OF IMINES [J].

KANG, GJ ;

CULLEN, WR ;

FRYZUK, MD ;

JAMES, BR ;

KUTNEY, JP .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (22) :1466-1467

[9]

MASUMA K, 1989, J CHEM SOC CHEM COMM, P1208

[10]

MORRISON JD, 1985, ASYMMETRIC SYNTHESIS, V5

← 1 2 →