BUSNCL3-MEDIATED REACTION OF 3-(TRIBUTYLSTANNYL)CYCLOALKENES WITH ALDEHYDES - HIGHLY ERYTHROSELECTIVE 2-CYCLOPENTENYLATION AND 2-CYCLOHEXENYLATION OF AROMATIC-ALDEHYDES

被引：11

作者：

MIYAKE, H

YAMAMURA, K

机构：

来源：

CHEMISTRY LETTERS | 1992年 / 11期

关键词：

D O I：

10.1246/cl.1992.2221

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

3-(Butyldichlorostannyl)cyclopentene and 3-(butyldichlorostannyl)cyclohexene, which are prepared by the transmetalation of corresponding 3-(tributylstannyl)cycloalkene with BuSnCl3, react with aromatic aldehydes to give 2-cycloalkenylated products with excellent erythro-selectivity. However, the corresponding reaction with aliphatic aldehydes proceeded in only moderate erythro-selectivity.

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页码：2221 / 2222

页数：2

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