ELECTROCHEMICAL CONVERSION OF CARBON-DIOXIDE TO METHANOL WITH USE OF ENZYMES AS BIOCATALYSTS

被引：29

作者：

KUWABATA, S ^{[1
]}

TSUDA, R ^{[1
]}

NISHIDA, K ^{[1
]}

YONEYAMA, H ^{[1
]}

机构：

[1] OSAKA UNIV, FAC ENGN, DEPT APPL CHEM, YAMADA OKA 2-1, SUITA, OSAKA 565, JAPAN

来源：

CHEMISTRY LETTERS | 1993年 / 09期

关键词：

D O I：

10.1246/cl.1993.1631

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Electrolysis of carbon dioxide-saturated phosphate buffer solution (pH 7) in the presence of formate dehydrogenase and methanol dehydrogenase as electrocatalysts together with methylviologen as an electron relay yielded formaldehyde and methanol as the reduction products of carbon dioxide under suitable electrolysis conditions, and the use of pyrrolo-quinoline quinone in place of methylviologen as the electron relay afforded selective reduction of carbon dioxide to methanol.

引用

页码：1631 / 1634

页数：4

共 18 条

[1] ELECTROCHEMICAL REDUCTION OF CARBON-DIOXIDE ON VARIOUS METAL-ELECTRODES IN LOW-TEMPERATURE AQUEOUS KHCO3 MEDIA [J].

AZUMA, M ;

HASHIMOTO, K ;

HIRAMOTO, M ;

WATANABE, M ;

SAKATA, T .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1990, 137 (06) :1772-1778

[2] ELECTROCHEMICAL REDUCTION OF CARBON-DIOXIDE ON CONDUCTIVE METALLIC OXIDES [J].

BANDI, A .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1990, 137 (07) :2157-2160

[3] ELECTROCATALYTIC REDUCTION OF CO2 BY NI CYCLAM2+ IN WATER - STUDY OF THE FACTORS AFFECTING THE EFFICIENCY AND THE SELECTIVITY OF THE PROCESS [J].

BELEY, M ;

COLLIN, JP ;

RUPPERT, R ;

SAUVAGE, JP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (24) :7461-7467

[4] ELECTROCATALYTIC REDUCTION OF CARBON-DIOXIDE BY 2,2'-BIPYRIDINE COMPLEXES OF RHODIUM AND IRIDIUM [J].

BOLINGER, CM ;

STORY, N ;

SULLIVAN, BP ;

MEYER, TJ .

INORGANIC CHEMISTRY, 1988, 27 (25) :4582-4587

[5]

FREESE KW, 1985, J ELECTROCHEM SOC, V132, P259

[6] REDUCTION OF CO2 ON N-GAAS ELECTRODES AND SELECTIVE METHANOL SYNTHESIS [J].

FRESE, KW ;

CANFIELD, D .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1984, 131 (11) :2518-2522

[7] MECHANISMS OF DECOMPOSITION OF SEMICONDUCTORS BY ELECTROCHEMICAL OXIDATION AND REDUCTION [J].

GERISCHE.H ;

MINDT, W .

ELECTROCHIMICA ACTA, 1968, 13 (06) :1329-&

[8]

HOPNER T, 1982, METHOD ENZYMOL, V89, P531

[9] FORMATION OF HYDROCARBONS IN THE ELECTROCHEMICAL REDUCTION OF CARBON-DIOXIDE AT A COPPER ELECTRODE IN AQUEOUS-SOLUTION [J].

HORI, Y ;

MURATA, A ;

TAKAHASHI, R .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1989, 85 :2309-2326

[10] CATALYTIC REDUCTION OF CO2 AT CARBON ELECTRODES MODIFIED WITH COBALT PHTHALOCYANINE [J].

LIEBER, CM ;

LEWIS, NS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (17) :5033-5034

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