SYNTHESIS AND CHARACTERIZATION OF TETRA(TERT-BUTYL)-2,3-ANTHRACENOCYANINATOIRON(II) COMPOUNDS

被引：8

作者：

HANACK, M

DIEING, R

ROHRIG, U

机构：

来源：

CHEMISTRY LETTERS | 1993年 / 03期

关键词：

D O I：

10.1246/cl.1993.399

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Bis(isocyanide) and bis(pyridine) complexes of tetra(tert-butyl)-2,3-anthracenocyaninatoiron(II) were synthesized from 6-tert-butyl-2,3-dicyanoanthracene and characterized by UV/Vis, NMR, and Mossbauer spectroscopy. Linear annulation of benzene rings to the phthalocyanine macrocycle produces a bathochromic shift of the Q-band. The first oxidation potential of the 2,3-anthracenocyanine macrocycle determined by cyclic voltammetry is lower than that of 2,3-naphthalocyanine.

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页码：399 / 402

页数：4

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