CHARACTERIZATION OF METAL-OXYGEN BRIDGE SYSTEMS

被引:179
作者
WING, RM
CALLAHAN, KP
机构
[1] Department of Chemistry, University of California, Riverside
关键词
D O I
10.1021/ic50074a034
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The vibrational spectra of various types of metal-oxygen bridge systems are assigned by normal-coordinate analysis and discussed in terms of geometry. The results of this analysis are shown to be a powerful tool for the characterization of metal-oxygen bridged complexes. The synthesis of a new dioxo-bridged molybdenum(V) complex is described and a structure is proposed on the basis of its infrared spectrum. © 1969, American Chemical Society. All rights reserved.
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页码:871 / &
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