PREPARATIVE DERIVATIZATION OF ENDO-DICYCLOPENTADIENE VIA METALATION

被引：2

作者：

KUMAGAI, T

AGA, M

OKADA, K

ODA, M

机构：

[1] OSAKA UNIV, FAC SCI, DEPT CHEM, TOYONAKA, OSAKA 560, JAPAN

[2] EHIME UNIV, FAC EDUC, DEPT CHEM, MATSUYAMA, EHIME 790, JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1991年 / 64卷 / 04期

关键词：

D O I：

10.1246/bcsj.64.1428

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

endo-Dicyclopentadiene has been selectively metallated with the base complex BuLi.t-BuOK in hexane at the olefinic positions in the norbornene moiety and a number of derivatives prepared by reaction of the metallated intermediate with electrophilic reagents. In particular, bromodicyclopentadiene thus obtained is a useful stock precursor for lithiodicyclopentadiene.

引用

页码：1428 / 1430

页数：3

共 7 条

[1] UBER DIE KONSTITUTION DER CYCLOPENTADIEN-CARBONSAURE AUS CYCLOPENTADIEN-KALIUM [J].