PREPARATION AND STUDY ON NEW FUNCTIONAL ALLYL ORGANOZINC DERIVATIVES

被引：13

作者：

LAMBERT, F

KIRSCHLEGER, B

VILLIERAS, J

机构：

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 405卷 / 03期

关键词：

D O I：

10.1016/0022-328X(91)86287-Z

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Stable organozinc compounds derived from alkyl-3-alkyl-2-(bromomethyl)-propenoates have been prepared. NMR C-13, H-1 and IR studies show only one Z stereoisomer (no methylenic form) with a strong chelation between zinc and the carbonyl oxygen of the ester and solvated by only one solvent molecule. Hydrolysis can be achieved by two concurrent mechanisms with or without transposition.

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页码：273 / 286

页数：14

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