AN EFFICIENT SYNTHESIS OF LITHIUM-SELECTIVE EXTRACTANTS - TERTIARY-ALKYL-14-CROWN-4 ETHERS

被引：22

作者：

SACHLEBEN, RA

DAVIS, MC

BRUCE, JJ

RIPPLE, ES

DRIVER, JL

MOYER, BA

机构：

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 34期

关键词：

D O I：

10.1016/S0040-4039(00)73912-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Highly-substituted crown ethers can be synthesized efficiently from tertiary and neopentyl diols. Nonamethyl-14-crown-4 and methyl-didecalino-14-crown-4 ethers are lipophilic and highly soluble in organic solvents and function as efficient, lithium-selective extractants.

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页码：5373 / 5376

页数：4

相关论文

共 11 条

[1] HIGH LITHIUM SELECTIVITY IN COMPETITIVE ALKALI-METAL SOLVENT-EXTRACTION BY LIPOPHILIC CROWN CARBOXYLIC-ACIDS [J].

BARTSCH, RA ;

CZECH, BP ;

KANG, SI ;

STEWART, LE ;

WALKOWIAK, W ;

CHAREWICZ, WA ;

HEO, GS ;

SON, B .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (17) :4997-4998

[2]

CREIGEE R, 1936, LIEBIGS ANN CHEM, V522, P75

[3] FUNCTIONALIZED 13-CROWN-4, 14-CROWN-4, 15-CROWN-4, AND 16-CROWN-4 COMPOUNDS - SYNTHESIS AND LITHIUM ION COMPLEXATION [J].

CZECH, BP ;

BABB, DA ;

SON, B ;

BARTSCH, RA .

JOURNAL OF ORGANIC CHEMISTRY, 1984, 49 (25) :4805-4810

[4] REDUCTION WITH METAL HYDRIDES .12. REDUCTION OF ACETALS AND KETALS WITH LITHIUM ALUMINUM HYDRIDE-ALUMINUM CHLORIDE [J].

ELIEL, EL ;

BADDING, VG ;

RERICK, MN .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1962, 84 (12) :2371-&

[5]

KAWAMURA N, 1979, TETRAHEDRON LETT, V6, P535

[6] HIGHLY SELECTIVE IONOPHORE FOR LITHIUM IONS - 14-CROWN-4 DERIVATIVE BEARING A LONG ALIPHATIC CHAIN [J].

KIMURA, K ;

KITAZAWA, S ;

SHONO, T .

CHEMISTRY LETTERS, 1984, (04) :639-640

[7] SYNTHESIS AND SELECTIVITY FOR LITHIUM OF LIPOPHILIC 14-CROWN-4 DERIVATIVES BEARING BULKY SUBSTITUENTS OR AN ADDITIONAL BINDING-SITE IN THE SIDE ARM [J].

KIMURA, K ;

YANO, H ;

KITAZAWA, S ;

SHONO, T .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1986, (12) :1945-1951

[8] LIPOPHILIC CROWN-4 DERIVATIVES AS LITHIUM IONOPHORES [J].

KITAZAWA, S ;

KIMURA, K ;

YANO, H ;

SHONO, T .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (23) :6978-6983

[9] DIDECALINO-14-CROWN-4 - HIGHLY LITHIUM ION-SELECTIVE EXTRACTANT [J].

KOBIRO, K ;

MATSUOKA, T ;

TAKADA, S ;

KAKIUCHI, K ;

TOBE, Y ;

ODAIRA, Y .

CHEMISTRY LETTERS, 1986, (05) :713-714

[10]

OLSHER U, 1982, J AM CHEM SOC, V104, P4007