STUDIES ON MIXED CHELATES .21. SYNTHESIS AND CRYSTAL-STRUCTURE OF THE BINUCLEAR NICKEL(II) COMPLEX, MU-(OXALATO)BIS[(ACETYLACETONATO)(N,N,N',N'-TETRAMETHYLETHYLENEDIAMINE)NICKEL(II)

被引：9

作者：

YAMADA, K

FUKUDA, Y

KAWAMOTO, T

KUSHI, Y

MORI, W

UNOURA, K

机构：

[1] OCHANOMIZU UNIV, FAC SCI, DEPT CHEM, OTSUKA, BUNKYO KU, TOKYO 112, JAPAN

[2] INST MOLEC SCI, COORDINAT CHEM LABS, OKAZAKI, AICHI 444, JAPAN

[3] OSAKA UNIV, COLL GEN EDUC, INST CHEM, TOYONAKA, OSAKA 560, JAPAN

[4] YAMAGATA UNIV, FAC SCI, DEPT CHEM, YAMAGATA 990, JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1993年 / 66卷 / 09期

关键词：

D O I：

10.1246/bcsj.66.2758

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new binuclear nickel(II) complex having the formula [Ni2(acac)2(tmen)2ox] (acac=acetylacetonate, tmen=N,N,N',N'-tetramethylethylenediamine, ox = oxalate) has been characterized, and its crystal structure. has been determined at room temperature. This crystal was obtained in its solvated form, [Ni2(acac)2(tmen)2ox].2TCE (where TCE=1,1,2,2-tetrachroloethane); orthorhombic system, space group Pcab (No. 61), with a=20.172(4), b= 17.180(5), c=13.132(3) angstrom, Z=4, R=0.044. The oxalate ligand acts as a bridging group between the two Ni(II) moieties.

引用

页码：2758 / 2761

页数：4

共 20 条

[1]

[Anonymous], 1974, INT TABLES XRAY CRYS, VIV

[2]

BALL PW, 1968, J CHEM SOC, P1405

[3] SYNTHESIS, CRYSTAL-STRUCTURE, MAGNETIC-PROPERTIES, AND THERMODYNAMIC AND ELECTROCHEMICAL STUDIES OF THE BINUCLEAR COMPLEX (MU-OXALATO)BIS[(1,4,8,11-TETRAAZACYCLOTETRADECANE)NICKEL(II)] NITRATE [J].