COMPLETE PROTON ASSIGNMENT IN ACETYLCHOLESTEROL USING GE-SELINCOR-TOCSY

被引：18

作者：

FACKE, T ^{[1
]}

BERGER, S ^{[1
]}

机构：

[1] UNIV MARBURG,DEPT CHEM,D-35032 MARBURG,GERMANY

来源：

TETRAHEDRON | 1995年 / 51卷 / 12期

关键词：

D O I：

10.1016/0040-4020(95)00094-O

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The ge-SELINCOR sandwich is used to select proton magnetization by irradiating the carbon atom directly bound to the proton. This magnetization can be transferred to coupled protons by a TOCSY mixing process (MLEV-16). A 1D experiment is obtained which gives additional information when complex H,H-COSY spectra suffer from overlapping crosspeaks. Coherence pathway selection is performed with pulsed field gradients.

引用

页码：3521 / 3524

页数：4

共 9 条

[1] MLEV-17-BASED TWO-DIMENSIONAL HOMONUCLEAR MAGNETIZATION TRANSFER SPECTROSCOPY [J].