A GENERAL-ROUTE TO SANDWICH AND HALF-SANDWICH TITANIUM IMIDO COMPLEXES - X-RAY STRUCTURE OF [TI(ETA(4)-ME(8)TAA)(NBU(T))] (ME(4)TAA=TETRAMETHYLDIBENZOTETRAAZA[14]ANNULENE)

被引：66

作者：

DUNN, SC ^{[1
]}

BATSANOV, AS ^{[1
]}

MOUNTFORD, P ^{[1
]}

机构：

[1] UNIV NOTTINGHAM,DEPT CHEM,NOTTINGHAM NG7 2RD,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 17期

关键词：

D O I：

10.1039/c39940002007

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The readily available complex [Ti(NBu(t))Cl-2(Bu(t)py)(2)](Bu(t)py = 4-tert-butylpyridine) is a useful precursor to a range of sandwich- and half-sandwich titanium imido derivatives including [Ti(eta-C(9)H(4)Me(3)) (NBu(t))Cl(Bu(t)py)] (C(9)H(4)Me(3) = trimethylindenyl), [Ti(eta-C5H5)(2)(NBu(t))(Bu(t)py)], [Ti(dmbpz)(NBu(t))Cl(Bu(t)py)] [dmbpz = tris(3,5-dimethylpyrazolyl) borate] and [Ti(eta(4)-Me(n)taa)(NBu(t))] {n = 4 or 8; Me((4 or 8))taa = (tetra- or octa-)methyl-dibenzotetraaza[14]annulene respectively}.

引用

页码：2007 / 2008

页数：2

共 29 条

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