TRI-TERT-BUTYLSILYLAMINES - SYNTHESIS, PHYSICAL-PROPERTIES AND NEW SILYLAMINE DERIVATIVES

被引：32

作者：

NOWAKOWSKI, PM ^{[1
]}

SOMMER, LH ^{[1
]}

机构：

[1] UNIV CALIF DAVIS,DEPT CHEM,DAVIS,CA 95616

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 178卷 / 01期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/S0022-328X(00)87863-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Tri-t-butylsilylamine has been synthesized in excellent yield from the hydrogenation of tri-t-butylsilylazide. The pKb values of the amine and its mono- and dimethyl derivatives have been quantitatively measured in 40% H2O/60% THF solution. Stable silylammonium salts, [(CH3)3C]3SiN+H3X- (X = Cl, Br, BF4) have been isolated and characterized. In addition, boron trihalide adducts of the amine, [(CH3)3C]3SiNH2 → BX3 (X = F, Cl), have been isolated and studied. © 1979.

引用

收藏

页码：95 / 103

页数：9

相关论文

共 31 条

[1] Hydrazoic acid and its inorganic derivatives [J].

Audrieth, LF .

CHEMICAL REVIEWS, 1934, 15 (02) :169-224

[2]

AUGUSTINE RL, 1965, CATALYTIC HYDROGENAT, P90

[3] PREPARATION AND PROPERTIES OF DIMETHYLAMINO- AND DIETHYLAMINOSILANE [J].

AYLETT, BJ ;

EMSLEY, J .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1967, (04) :652-&

[4] RELATIVE STABILITIES OF SOME COMPLEXES OF DIMETHYL-AMINO-SILANES AND -METHANES WITH LEWIS ACIDS [J].

AYLETT, BJ ;

PETERSON, LK .

JOURNAL OF THE CHEMICAL SOCIETY, 1965, (JUL) :4043-&

[5] PHOSPHINE AND ARSINE DERIVATIVES OF MONOSILANE [J].

AYLETT, BJ ;

EMELEUS, HJ ;

MADDOCK, AG .

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1955, 1 (03) :187-193

[6] ZUR KENNTNIS DER CHEMIE DER SILAZANE .3. UBER DIE REAKTIONEN VON SILAZANEN MIT TRIHALOGENIDEN DER 3. UND 5. GRUPPE [J].

BECKEGOEHRING, M ;

KRILL, H .

CHEMISCHE BERICHTE-RECUEIL, 1961, 94 (04) :1059-1063

[7]

COATES GE, 1952, J CHEM SOC, P2347

[8]

DEXHEIMER EM, 1975, J ORGANOMET CHEM, V102, P21

[9] HINDERED ORGANOSILICON COMPOUNDS - SYNTHESIS AND PROPERTIES OF DI-TERT-BUTYLSILANE, DI-TERT-BUTYLMETHYLSILANE, AND TRI-TERT-BUTYLSILANES [J].

DOYLE, MP ;

WEST, CT .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (13) :3777-3782

[10] SILANE REDUCTIONS IN ACIDIC MEDIA .4. REDUCTIONS OF ALKYL-SUBSTITUTED CYCLOHEXANONES BY MONOALKYLSILANES, DIALKYLSILANES, AND TRIALKYLSILANES - STEREOCHEMISTRY OF ALCOHOL AND ETHER FORMATION [J].

DOYLE, MP ;

WEST, CT .

JOURNAL OF ORGANIC CHEMISTRY, 1975, 40 (26) :3821-3829

← 1 2 3 4 →