2,4,6-TRI-TERT-BUTYLNITROSOBENZENE AS A SPIN TRAP AND AN ELECTRON AND HOLE SCAVENGER IN A 3-METHYLPENTANE MATRIX

被引：14

作者：

MURABAYASHI, S ^{[1
]}

SHIOTANI, M ^{[1
]}

SOHMA, J ^{[1
]}

机构：

[1] HOKKAIDO UNIV,FAC ENGN,SAPPORO,HOKKAIDO 060,JAPAN

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1979年 / 83卷 / 07期

关键词：

D O I：

10.1021/j100470a016

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

2,4,6-Tri-tert-butylnitrosobenzene (BNB), which is known as a good spin- trapping agent, was found to be a scavenger for electrons and holes in glassy alkanes. By spin trapping experiments on 3-methylpentane (3-MP) containing BNB the species produced by γ irradiation of 3-MP were indentified. Based on this identification, mechanisms for the γ radiolysis of 3-MP and for the photolysis of 3-MP containing the photosensitizer N,N,N′,N′-tetramethyl-p-phenylenediamine are discussed. © 1979 American Chemical Society.

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页码：844 / 849

页数：6

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