METHYL DITHIOCARBAMATE GOLD(I) AND GOLD(III) COMPLEXES - SYNTHESIS AND REACTIVITY WITH AMINES

被引：16

作者：

BARDAJI, M ^{[1
]}

LAGUNA, A ^{[1
]}

LAGUNA, M ^{[1
]}

MERCHAN, F ^{[1
]}

机构：

[1] UNIV ZARAGOZA,CSIC,INST CIENCIA MAT ARAGON,DEPT QUIM INORGAN,E-50009 ZARAGOZA,SPAIN

来源：

INORGANICA CHIMICA ACTA | 1994年 / 215卷 / 1-2期

关键词：

GOLD COMPLEXES; DITHIOCARBAMATE COMPLEXES;

D O I：

10.1016/0020-1693(93)03688-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of several methyl dithiocarbamates {S(MeS)CNHR} (R=p-MeC(6)H(4), o-MeC(6)H(4), p-MeOC(6)H(4) and 3,5-Me(2)C(6)H(3)) with Au(C6F5)(tht) and Au(C6F5)(3)(OEt(2)) gives the suitable complexes containing S-bonded ligands. Thioacylation of primary amines is reported, through a reaction in the coordinated ligands; the new ligands hold the coordination to the gold atom.

引用

页码：215 / 218

页数：4

共 11 条

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