ORGANIC ELECTRONIC CONDUCTORS AND PRECURSORS .15. NOVEL DITHIOLENE NICKEL-COMPLEXES BASED ON BENZENEHEXATHIOLATE DERIVATIVES

被引：8

作者：

FANGHANEL, E

BIERWISCH, J

RICHTER, AM

BEYE, N

机构：

[1] Institut für Organische Chemie der Technischen Hochschule Leuna-Merseburg

来源：

SYNTHETIC METALS | 1992年 / 47卷 / 01期

关键词：

D O I：

10.1016/0379-6779(92)90334-F

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Dithiolato-nickel complexes with multisulfur ligands derived from benzenehexathiolate have been synthesized. The properties of the monomeric and polymeric complexes have been characterized by ESR spectroscopic and magnetochemical data and by electrical conductivity measurements. The prepared complexes are paramagnetic and have characteristic absorptions between 800 and 1000 nm.

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页码：87 / 93

页数：7

相关论文

共 14 条

[1] DIMERIZATION AND STACKING IN TRANSITION-METAL BISDITHIOLENES AND TETRATHIOLATES [J].

ALVAREZ, S ;

VICENTE, R ;

HOFFMANN, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (22) :6253-6277

[2] ESR STUDIES OF 4 COORDINATE COMPLEXES OF NICKEL,PALLADIUM AND PLATINUM RELATED BY ELECTRON TRANSFER REATIONS [J].

DAVISON, A ;

MAKI, AH ;

EDELSTEIN, N ;

HOLM, RH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1963, 85 (13) :2029-&

[3] ELECTRONIC STRUCTURES OF SQUARE-PLANAR METAL COMPLEXES .3. HIGH-SPIN PLANAR COBALT (I) AND IROM (I) [J].

GRAY, HB ;

BILLIG, E .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1963, 85 (13) :2019-&

[4] CRYSTAL-STRUCTURE OF (TTF)2NIS4C4H4 [J].

KASPER, JS ;

INTERRANTE, LV ;

SECAUR, CA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (04) :890-891

[5] FRAGMENTATION OF ARYL ALKYL SULFIDES - A SIMPLE, ONE-POT SYNTHESIS OF POLYMERCAPTOBENZENES FROM POLYCHLOROBENZENES [J].

MAIOLO, F ;

TESTAFERRI, L ;

TIECCO, M ;

TINGOLI, M .

JOURNAL OF ORGANIC CHEMISTRY, 1981, 46 (15) :3070-3073

[6]

MAKI HA, 1966, J AM CHEM SOC, V88, P1080

[7] TETRATHIAFULVALENES .19. SYNTHESIS AND PROPERTIES OF ELECTRON CONDUCTING POLY-DITHIOLENE COMPLEXES WITH ETHYLENE TETRATHIOLAT AND TETRATHIAFULVALENE TETRATHIOLAT AS BRIDGE LIGANDS [J].

POLESCHNER, H ;

JOHN, W ;

HOPPE, F ;

FANGHANEL, E ;

ROTH, S .

JOURNAL FUR PRAKTISCHE CHEMIE, 1983, 325 (06) :957-975

[8]

RIBAS J, 1981, CR ACAD SCI II, V293, P665

[9]

RIBAS J, 1981, CR ACAD SCI II, V293, P287

[10]

RICHTER AM, 1990, SYNTHESIS-STUTTGART, P1149