Electron spin resonance and the non-bonding orbitals of the phosphorescent state of pyrazine

被引：50

作者：

Sharnoff, M. ^{[1
]}

机构：

[1] Univ Delaware, Dept Phys, Newark, DE 19711 USA

来源：

CHEMICAL PHYSICS LETTERS | 1968年 / 2卷 / 07期

关键词：

D O I：

10.1016/0009-2614(65)80022-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We have used a microwave-optical double quantum method to investigate the electron spin resonance of the phosphorescent state of pyrazine as a guest in paradichlorbenzene. The fine structure tensor of pyrazine has approximate axial symmetry about the in-plane axis normal to the N-N direction. The fine structure parameters are D = -(0.309 +/- 0.001) cm(-1) and E = +(0.006 +/- 0.002) cm(-1).

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页码：498 / 500

页数：3

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