A MANY-BODY STOCHASTIC APPROACH TO ROTATIONAL MOTIONS IN LIQUIDS - COMPLEX DECAY TIMES IN HIGHLY VISCOUS FLUIDS

被引：17

作者：

POLIMENO, A

FREED, JH

机构：

[1] Baker Laboratory of Chemistry, Cornell University, Ithaca

来源：

CHEMICAL PHYSICS LETTERS | 1990年 / 174卷 / 05期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/S0009-2614(90)87183-R

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A two-body Smoluchowski equation, including a solute molecule and a collective solvent mode, is developed for studying reorientational dynamics in complex fluids. Multiexponential decay correlation functions for first- and second-rank observables are computed. They exhibit bifurcation and other properties related to typical observations on glassy and supercooled liquids. © 1990.

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页码：481 / 488

页数：8

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