SYNTHESIS AND NMR-SPECTROSCOPY OF 5-COORDINATE PLATINUM(II) HYDRIDE COMPLEXES

被引：11

作者：

HANDLER, A

PERINGER, P

MULLER, EP

机构：

[1] UNIV INNSBRUCK,INST ANORGAN & ANALYT CHEM,A-6020 INNSBRUCK,AUSTRIA

[2] UNIV INNSBRUCK,INST ORGAN & PHARMAZEUT CHEM,A-6020 INNSBRUCK,AUSTRIA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 412卷 / 03期

关键词：

D O I：

10.1016/0022-328X(91)86090-D

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of [Pt{PhP(CH2CH2PPh2)2}(PPh3)](O3SCF3)2 with NaBH4 gives the five-coordinate platinum hydride complex [PtH{PhP(CH2CH2PPh2)2)(PPh3)]+ or [Pt{PhP(CH2CH2PPh2)2}(PPh3)] depending on the reaction conditions. The zerovalent complex and the hydride are readily interconverted. The hydride complexes [PtH{PhP(CH2CH2PPh2)2}L]+, L = PBu3, PPh2H, PCy2H (Cy = cyclohexyl) and Ph2PCH2PPh2 have also been prepared.

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页码：451 / 456

页数：6

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