ELECTRON SPIN-ECHO-DETECTED EXCITATION SPECTROSCOPY OF MANGANESE-DOPED BA-3(VO4)(2) - IDENTIFICATION OF TETRAHEDRAL MN5+ AS THE ACTIVE LASER CENTER

被引：39

作者：

BUIJSSE, B

SCHMIDT, J

CHAN, IY

SINGEL, DJ

机构：

[1] BRANDEIS UNIV,DEPT CHEM,WALTHAM,MA 02138

[2] MONTANA STATE UNIV,DEPT CHEM & BIOCHEM,BOZEMAN,MT 59717

来源：

PHYSICAL REVIEW B | 1995年 / 51卷 / 10期

关键词：

D O I：

10.1103/PhysRevB.51.6215

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Electron-spin-echo spectroscopy on the lowest 3A2 state of Mn5+ ions in Ba3(VO4)2 in combination with pulsed laser excitation at 1176.6 nm proves that the laser activity in this material derives from the 1E3A2 transition of the Mn5+ ion. This result is corroborated by Zeeman experiments on the 1E→3A2 emission line, which further reveal the Zeeman splitting of the 1E state. © 1995 The American Physical Society.

引用

页码：6215 / 6220

页数：6

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