RAMAN-SPECTROSCOPY OF PCL5 .1. SYSTEM PCL5-TICL4

被引：14

作者：

DEMIRAY, AF

BROCKNER, W

机构：

[1] Anorganisch-Chemisches Institut, Technische Universität Clausthal

来源：

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | 1979年 / 35卷 / 06期

关键词：

D O I：

10.1016/0584-8539(79)80124-5

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

The temperature dependent behavior of the binuclear halogen-bridged compounds (PCl4)2Ti2-Cl10 and PCl4Ti2Cl9 has been investigated by Raman spectroscopy. The dimer-monomer conversion (PCl4)2Ti2Cl10⇌2PCl4TiCl5 has been found in the solid state. TiCl5- and PCl4+ ions are present in the melt. Molten PCl4Ti2Cl9 decomposes in solid PCl4TiCl5 and gaseous TiCl4. All processes are reversible. © 1979.

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页码：659 / 662

页数：4

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