COMPLEX CHEMISTRY OF REACTIVE ORGANIC-COMPOUNDS .26. SYNTHESIS OF CARBOCYCLIC CARBENE COMPLEXES BY METAL-INDUCED DIAZOCYCLOPENTADIENE FRAGMENTATION

被引：23

作者：

HERRMANN, WA ^{[1
]}

PLANK, J ^{[1
]}

ZIEGLER, ML ^{[1
]}

WEIDENHAMMER, K ^{[1
]}

机构：

[1] UNIV HEIDELBERG,INST ANORGAN CHEM,D-6900 HEIDELBERG 1,FED REP GER

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1978年 / 17卷 / 10期

关键词：

D O I：

10.1002/anie.197807771

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first metal complex to contain an oligocyclic dicarbene is formed as a result of a hitherto unobserved [2+2] cycloaddition of the carbene liberated from 1. The structure of 2 is confirmed by X‐ray structure analysis. (Figure Presented.) Copyright © 1978 by Verlag Chemie, GmbH, Germany

引用

页码：777 / 778

页数：2

共 5 条

[1] COMPLEX CHEMISTRY OF REACTIVE ORGANIC-COMPOUNDS .22. ORGANOMETALLIC CYCLOPENTADIENYLATIONS WITH DIAZOCYCLOPENTADIENES - SYNTHESES OF BETA-HALOCYCLOPENTADIENYL)IRON COMPLEXES
HERRMANN, WA
HUBER, M
[J]. CHEMISCHE BERICHTE-RECUEIL, 1978, 111 (09): : 3124 - 3135
[2] COMPLEX CHEMISTRY OF REACTIVE ORGANIC-COMPOUNDS .25. STABILIZATION OF DIPHENYLMETHYLENE AND DIPHENYLDIAZOMETHANE IN CARBONYL COBALT COMPLEXES
HERRMANN, WA
SCHWEIZER, I
[J]. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1978, 33 (08): : 911 - 914
[3] HERRMANN WA, ANGEW CHEM
[4] REDHOUSE AD, 1975, J ORGANOMET CHEM, V99, pC29
[5] Regitz M, 1977, DIAZOALKANE EIGENSCH

← 1 →