HBR CLEAVAGE OF CUBANE-1,4-DICARBOXYLIC ACID - EASY ENTRY INTO THE NORTHWISTBRENDANE(ENE) SYSTEM

被引：12

作者：

EATON, PE ^{[1
]}

MILLIKAN, R ^{[1
]}

ENGEL, P ^{[1
]}

机构：

[1] UNIV BERN,CHEM & MINERAL KRISTALLOG LAB,CH-3012 BERN,SWITZERLAND

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1990年 / 55卷 / 09期

关键词：

D O I：

10.1021/jo00296a048

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Addition of hydrogen bromide occurs twice over on heating cubane-l,4-dicarboxylic acid with HBr in HOAc giving in good yield a nortwistbrendane (tricyclo[4.2.0.03,8]octane, C2-bissecocubane) derivative. Further transformations easily give simply substituted nortwistbrendenes. © 1990, American Chemical Society. All rights reserved.

引用

页码：2823 / 2826

页数：4

共 19 条

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