FLEXIBILITY OF THE ZEOLITE RHO FRAMEWORK - RELOCATION OF CADMIUM ACCOMPANYING TRANSFORMATION OF THE UNIT-CELL AT HIGH-TEMPERATURES

被引:17
作者
PARISE, JB
XING, L
CORBIN, DR
机构
[1] SUNY STONY BROOK,DEPT EARTH & SPACE SCI,STONY BROOK,NY 11794
[2] DUPONT CO INC,CENT RES & DEV,WILMINGTON,DE 19880
关键词
D O I
10.1039/c39910000162
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Upon heating Cd2+-exchanged zeolite RHO, a relocation of the extra-framework cation accompanies the transformation from the acentric (A) to centric (C) structure type; this relocation from the eight ring to a six ring site, which are 5.7 angstrom apart, is the largest observed in a zeolite.
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页码:162 / 163
页数:2
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