(H2O)2 - SPECTROSCOPY, STRUCTURE AND DYNAMICS

被引：131

作者：

FRASER, GT

机构：

[1] Molecular Physics Division, National Institute of Standards and Technology, Gaithersburg, MD

来源：

INTERNATIONAL REVIEWS IN PHYSICAL CHEMISTRY | 1991年 / 10卷 / 02期

关键词：

D O I：

10.1080/01442359109353257

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Tunnelling in water dimer allows each of the hydrogen atoms to participate in the hydrogen bonding, giving rise to a complicated energy-level scheme and rotational spectrum. As a result of new theoretical and experimental developments, great progress has been made in the analysis and interpretation of this spectrum, yielding detailed information about this hydrogen-bonded interaction. This paper reviews the spectroscopy of this highly non-rigid dimer, which is becoming a prototype systems for the study of multidimensional tunnelling problems in weakly bound complexes.

引用

页码：189 / 206

页数：18

共 57 条

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