ENANTIOSELECTIVE CATALYSIS .59. ADDITIONAL OF OPTICALLY-ACTIVE P-H COMPOUNDS TO P-SUBSTITUTED OLEFINS

被引：25

作者：

BRUNNER, H

LIMMER, S

机构：

[1] Institut für Anorganische Chemie, Universität Regensburg, W-8400 Regensburg

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 413卷 / 1-3期

关键词：

D O I：

10.1016/0022-328X(91)80038-L

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The base-catalyzed addition of the optically active P-H phospholanes tarpholane and diopholane to olefins activated by diphenylphosphino or diphenylphosphinoyl groups gives unsymmetrical chelate phosphines which are used as cocatalysts in the hydrogenation of (Z)-alpha-N-acetamidocinnamic acid, in the cross-coupling of 1-phenylethyl Grignard with vinylbromide, and in the hydrosilylation of acetophenone with diphenylsilane.

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页码：55 / 63

页数：9

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