PI-COORDINATION OF DIORGANOTIN DICATIONS

被引：66

作者：

WRACKMEYER, B ^{[1
]}

KEHR, G ^{[1
]}

BOESE, R ^{[1
]}

机构：

[1] UNIV ESSEN GESAMTHSCH, INST ANORGAN CHEM, W-4300 ESSEN 1, GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1991年 / 30卷 / 10期

关键词：

D O I：

10.1002/anie.199113701

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The understanding of the mechanism of organoboration in 1 rests on the stabilization of the diorganotin dication by two C-C triple bonds. Compound 1 where R = Me was isolated from tetra-1-propynylstannane and triethyl borane. X-ray analysis shows that the halves of the molecule are not exactly symmetric, but have different bond lengths and angles.

引用

页码：1370 / 1372

页数：3

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