A new entry to difluoromethylene compounds; An electrochemical method

被引：14

作者：

Asai, H ^{[1
]}

Uneyama, K ^{[1
]}

机构：

[1] OKAYAMA UNIV, FAC ENGN, DEPT APPL CHEM, OKAYAMA 700, JAPAN

来源：

CHEMISTRY LETTERS | 1995年 / 12期

关键词：

D O I：

10.1246/cl.1995.1123

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Electroreduction of dibromodifluoromethane in the presence of diphenyldiselenide and olefins in a DMF-(Pt)-(Al) system provided adducts of in situ generated bromodifluoromethyl radical and phenylselenenyl group to olefins. One electron transfer from benzeneselenolate to CF2Br2 induces the formation of CF2Br . radical. This system is also useful for generation of . CF(2)CO(2)Et radical from ethyl bromodifluoroacetate.

引用

页码：1123 / 1124

页数：2

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