X-RAY STRUCTURAL-ANALYSIS OF THE POLYHYDRIDE COMPLEX SALT [(PH3P)3IR(MU-H)3AG(MU-H)3IR(PH3P)3][O3SCF3]

被引：12

作者：

BACHECHI, F

机构：

[1] Istituto di Strutturistica Chimica G. Giacomello, CNR, Area delta Ricerca di Roma, Rome, CP10

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 474卷 / 1-2期

关键词：

IRIDIUM; SILVER; HYDRIDE; CLUSTER; X-RAY STRUCTURE;

D O I：

10.1016/0022-328X(94)84065-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The polyhydride complex [(Ph3P)3Ir(mu-H)3Ag(mu-H)3Ir(Ph3P)3]+ has been prepared and characterized as the trifluorosulfonate salt. It crystallizes in the triclinic P1BAR space group with z = 1; a = 10.100(4), b = 14.940(4), c = 15.309(5) angstrom; alpha = 116.53(4), beta = 94.55(4), gamma = 108.43(4)-degrees and V= 2643 angstrom3. The structure consists of a cluster with a linear Ir-Ag-Ir array. The hydride ligands were not located but from the arrangement of the heavy atoms their most probable positions bridging the Ir-Ag interactions were obtained by potential energy methods.

引用

页码：191 / 197

页数：7

共 14 条

[1] GOLD AND SILVER HYDRIDES - SYNTHESIS OF HETEROBIMETALLIC IR-AU, IR-AG COMPLEXES AND X-RAY CRYSTAL-STRUCTURES OF [(PPH3)AU(MU-H)IRH2(PPH3)3](BF4) AND [(PPH3)AG(MU-H)IRH2(PPH3)3](CF3SO3) [J].