METAL-COMPLEXES OF BIOLOGICALLY IMPORTANT LIGANDS .53. CHIRAL HALF-SANDWICH COMPLEXES OF RHODIUM(III), IRIDIUM(III), IRIDIUM(I), AND RUTHENIUM(II) WITH ALPHA-AMINO-ACID ANIONS

被引:134
作者
KRAMER, R [1 ]
POLBORN, K [1 ]
WANJEK, H [1 ]
ZAHN, I [1 ]
BECK, W [1 ]
机构
[1] UNIV MUNICH,INST ANORGAN CHEM,MEISERSTR 1,W-8000 MUNICH 2,GERMANY
关键词
Rhodium(III) complexes / Iridium(I/III) complexes / Ruthenium(II) complexes / α‐Amino acid anion chelates / η[!sup]5[!/sup]‐Pentamethylcyclopentadienyl / η[!sup]6[!/sup]‐Benzene / η[!sup]4[!/sup]‐1,5‐Cyclooctadiene;
D O I
10.1002/cber.19901230420
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Metal Complexes of Biologically Important Ligands, LIII. – Chiral Half‐Sandwich Complexes of Rhodium(III), Iridium(III), Iridium(I), and Ruthenium(I1) with a‐Amino Acid Anions The chloro‐bridged metal compounds Cp*(Cl)M(μ‐Cl)2M(Cl)‐Cp* (M = Rh, Ir; Cp* = η5‐C5Me5), (η6‐C6H6)(Cl) Copyright © 1990 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim
引用
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页码:767 / 778
页数:12
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