EXPERIMENTAL PROBES OF DISSOCIATIVE STATES - FANO PROFILES IN THE STATE-SPECIFIC PHOTODISSOCIATION OF FNO

被引：51

作者：

BRANDON, JT

REID, SA

ROBIE, DC

REISLER, H

机构：

[1] Chemistry Department, University of Southern California, Los Angeles

来源：

JOURNAL OF CHEMICAL PHYSICS | 1992年 / 97卷 / 07期

关键词：

D O I：

10.1063/1.463824

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We have observed strongly asymmetric features in the S1 <-- S0 state-specific photofragment yield spectrum of jet-cooled FNO. We interpret these as Fano profiles, arising from interference between direct and indirect dissociation following excitation to a region near the top of a barrier on the S1 potential energy surface.

引用

收藏

页码：5246 / 5249

页数：4

相关论文

共 13 条

[1]

BLATT JM, 1952, THEORETICAL NUCLEAR, P379

[2] ULTRAVIOLET-ABSORPTION SPECTROSCOPY OF DISSOCIATING MOLECULES - EFFECTS OF CLUSTER FORMATION ON THE PHOTODISSOCIATION OF CH3I [J].

DONALDSON, DJ ;

VAIDA, V ;

NAAMAN, R .

JOURNAL OF CHEMICAL PHYSICS, 1987, 87 (05) :2522-2530

[3] EFFECTS OF CONFIGURATION INTERACTION ON INTENSITIES AND PHASE SHIFTS [J].

FANO, U .

PHYSICAL REVIEW, 1961, 124 (06) :1866-&

[4] THEORETICAL INVESTIGATION OF THE PHOTODISSOCIATION DYNAMICS OF HONO - VIBRATIONAL PREDISSOCIATION IN THE ELECTRONICALLY EXCITED-STATE S-1 [J].

HENNIG, S ;

UNTCH, A ;

SCHINKE, R ;

NONELLA, M ;

HUBER, JR .

CHEMICAL PHYSICS, 1989, 129 (01) :93-107

[5]

LEFEBVREBRION H, 1986, PERTURBATIONS SPECTR, P331

[6]

MASSEY HSW, 1969, ELECTRON IONIC IMP, V1, P594

[7] CONFIGURATION INTERACTION THEORY . EFFECTS OF OVERLAPPING RESONANCES [J].

MIES, FH .

PHYSICAL REVIEW, 1968, 175 (01) :164-&

[8] MAPPING OF PARENT TRANSITION-STATE WAVE-FUNCTIONS INTO PRODUCT ROTATIONS - AN EXPERIMENTAL AND THEORETICAL INVESTIGATION OF THE PHOTODISSOCIATION OF FNO [J].

OGAI, A ;

BRANDON, J ;

REISLER, H ;

SUTER, HU ;

HUBER, JR ;

VONDIRKE, M ;

SCHINKE, R .

JOURNAL OF CHEMICAL PHYSICS, 1992, 96 (09) :6643-6653

[9] VIBRATIONAL PREDISSOCIATION IN THE CO2 DIMER AND TRIMER AND RARE GAS-CO2 COMPLEXES [J].

PINE, AS ;

FRASER, GT .

JOURNAL OF CHEMICAL PHYSICS, 1988, 89 (01) :100-109

[10] INTERFERENCE DIPS IN MOLECULAR ABSORPTION-SPECTRA CALCULATED FOR COUPLED ELECTRONIC STATE POTENTIAL SURFACES [J].

REBER, C ;

ZINK, JI .

JOURNAL OF CHEMICAL PHYSICS, 1992, 96 (04) :2681-2690