SYNTHESIS AND STRUCTURE OF UNPRECEDENTED CU(I)4RH(III)4 AND CU(I)4IR(III)4 S-BRIDGED POLYNUCLEAR COMPLEXES CONTAINING MU-2-THIOLATO AND MU-3-THIOLATO AND COORDINATED DISULFIDE - SPONTANEOUS REDUCTION OF COPPER(II) TO TRIGONAL-PLANAR COPPER(I)

被引：32

作者：

KONNO, T

OKAMOTO, K

HIDAKA, J

机构：

[1] Department of Chemistry, University of Tsukuba, Ibaraki 305, Tsukuba

来源：

INORGANIC CHEMISTRY | 1992年 / 31卷 / 19期

关键词：

D O I：

10.1021/ic00045a003

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Unprecedented C2-cage-type S-bridged polynuclear complexes containing mu-2- and mu-3-thiolato and coordinated disulfide, [Cu(I)(4){M(aet)3}2{M2(aet)4(cysta)}]6+ (M = Rh(III) or Ir(III), aet = 2-aminoethanethiolate, and cysta = cystamine), were produced from the facile reactions of fac(S)-[M(aet)3] and Cu2+. X-ray analytical and C-13 NMR spectral data indicated the selective formation of a pair of quasi-mesotype enantiomers having C2 symmetry.

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页码：3875 / 3876

页数：2

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