SRN1 C-ARYLATION OF POTASSIUM ARYLOXIDES BY ARYLAZO PHENYL OR TERT-BUTYL SULFIDES IN DMSO

被引：30

作者：

PETRILLO, G

NOVI, M

DELLERBA, C

TAVANI, C

BERTA, G

机构：

来源：

TETRAHEDRON | 1990年 / 46卷 / 23期

关键词：

D O I：

10.1016/S0040-4020(01)90095-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Aryloxide ions (Ar'O-) behave as C-nucleophiles towards diazosulfides (ArN=NSR; R = Ph, But) leading to unsymmetrical hydroxybiaryls (ArAr'OH) via C-C coupling. The reaction is particularly suited for the synthesis of terms which contain electron-withdrawing groups on the Ar moiety. The SRN1 mechanism is proposed on the grounds of experimental evidences. © 1990.

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页码：7977 / 7990

页数：14

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