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OXIDATION OF N-ALKYLAMIDES TO NOVEL HYDROPEROXIDES BY DIOXYGEN

被引：68
作者：
DRAGO, RS
RILEY, R
机构：
[1] Department of Chemistry, University of Florida, Gainesville
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1990年 / 112卷 / 01期
关键词：
D O I：
10.1021/ja00157a034
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
We report the facile, uncatalyzed, oxidation of 1 -methyl-2-pyrrolidinone by 02 at 75 °C and 3 atm pressure. Approximately 2 M concentrations of an oxidizing agent are formed in the neat solvent, dept and apt l3C NMR as well as mass spectral analysis indicate that 5-hydroperoxo-1 -methyl-2-pyrrolidinone is formed. The hydroperoxide is converted to 1 -methylsuccinimide by peroxide decomposition catalysts. © 1990, American Chemical Society. All rights reserved.
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页码：215 / 218
页数：4
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