CATHODIC REDUCTION PATHWAYS OF HALOAROMATICS .3. HALONITROBENZENES

被引：68

作者：

NELSON, RF

CARPENTE.AK

SEO, ET

机构：

[1] UNIV IDAHO,DEPT CHEM,MOSCOW,ID 83843

[2] TRW INC,TRW SYST GRP,REDONDO BEACH,CA 90278

来源：

JOURNAL OF THE ELECTROCHEMICAL SOCIETY | 1973年 / 120卷 / 02期

关键词：

D O I：

10.1149/1.2403421

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

All of the monohalogenated nitrobenzenes have been studied in nonaqueous media using various electrochemical and spectroscopic methods. A mechanism involving halide elimination and hydrogen atom abstraction from the solvent to form nitrobenzene was verified by deuteration experiments employing electron paramagnetic resonance measurements. In addition to formation of nitrobenzene, azoxybenzenes and nitrobiphenyls could be generated under different experimental conditions. Possible electrosynthesis studies are also proposed based on these data.

引用

页码：206 / 210

页数：5

共 29 条

[1] NUANCES OF ECE MECHANISM .2. ADDITION HYDROCHLORIC ACID AND AMINES TO ELECTROCHEMICALLY GENERATED O-BENZOQUINONES [J].