FACILE AND SELECTIVE OXIDATION OF SULFIDES TO SULFOXIDES BY T-BUTYL HYDROPEROXIDE IN AQUEOUS-MEDIUM

被引：21

作者：

FRINGUELLI, F

PELLEGRINO, R

PIZZO, F

机构：

[1] Dipartimento di Chi mica, Universitä di Perugia, 06100 Perugia

来源：

SYNTHETIC COMMUNICATIONS | 1993年 / 23卷 / 22期

关键词：

D O I：

10.1080/00397919308011174

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The oxidation of sulfides to sulfoxides with TBHP in water only occurs selectively with high yields and permits the sulfoxides to be prepared without using organic solvents. When the reaction is performed in aqueous sulfuric acid with a H2SO4/sulfide molar ratio of 20/1, the oxidation rate is greatly increased.

引用

页码：3157 / 3163

页数：7

共 29 条

[1] ASYMMETRIC INDUCTION IN THE ADDITIONS OF ANIONS OF ALLYLIC SULFOXIDES TO BENZALDEHYDE
ANTONJUK, DJ
RIDLEY, DD
SMAL, MA
[J]. AUSTRALIAN JOURNAL OF CHEMISTRY, 1980, 33 (12) : 2635 - 2651
[2] BALICKI R, 1992, LIEBIGS ANN CHEM, P883
[3] OXIDATION OF ORGANIC SULPHIDES .6. THE PRODUCTS OF THE REACTION OF ORGANIC HYDROPEROXIDES WITH ALK-2-ENYL SULPHIDES
BARNARD, D
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1956, (MAR): : 489 - 495
[4] VALENCE VIBRATION FREQUENCIES AND HYDROGEN BOND FORMATION OF SULPHOXIDE AND SULPHONE GROUPS - (ABSORPTION SPECTRA AND STRUCTURE OF ORGANIC SULPHUR COMPOUNDS .5.
BARNARD, D
FABIAN, JM
KOCH, HP
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1949, (OCT): : 2442 - 2454
[5] BATEMAN L, 1954, P ROY SOC LOND A MAT, P224
[6] SYNTHESIS OF ARYL METHYL SULFOXIDES AND DETERMINATION OF THE CONJUGATIVE EFFECT OF THE METHYLSUFINYL GROUP
BORDWELL, FG
BOUTAN, PJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1957, 79 (03) : 717 - 722
[7] CAMPESINI S, 1990, CHIM IND MILANO
[8] CERANI A, 1960, GAZZ CHIM ITAL, P382
[9] CHONDARY BM, 1992, J MOL CATAL, V75, pL7
[10] CORDELLICCHIO C, 1992, J ORG CHEM, V57, P1718

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