SOLID-STATE REACTIONS IN BINARY-MIXTURES OF NANOMETER-SIZED PARTICLES

被引:4
作者
DICKENSCHEID, W [1 ]
BIRRINGER, R [1 ]
机构
[1] UNIV SAARLAND,INST WERKSTOFFPHY,D-66041 SAARBRUCKEN,GERMANY
关键词
D O I
10.1063/1.359037
中图分类号
O59 [应用物理学];
学科分类号
摘要
Solid-state reactions in mixtures of nanometer-sized Cu and Zr as well as Ni and Zr crystallites - produced by inert-gas condensation followed by in situ compaction - have been investigated by x-ray diffraction and thermal analysis. Nanocrystalline particle mixtures and multilayered samples showed qualitatively the same behavior: A solid-state amorphization reaction occurs in Ni xZr1-x samples but not in CuxZr1-x. The results are discussed in the framework of a heterogeneous nucleation and growth process for the amorphous phase. Comparison with results from ball-milling experiments and mechanically prepared multilayers reveals the significance of additional external driving forces. © 1995 American Institute of Physics.
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页码:533 / 539
页数:7
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