CALIBRATION TRANSFER ACROSS NEAR-INFRARED SPECTROMETRIC INSTRUMENTS USING SHENKS ALGORITHM - EFFECTS OF DIFFERENT STANDARDIZATION SAMPLES

被引:90
作者
BOUVERESSE, E
MASSART, DL
DARDENNE, P
机构
[1] FREE UNIV BRUSSELS,INST PHARMACEUT,B-1090 BRUSSELS,BELGIUM
[2] STN HAUTE BELG,B-6800 LIBRAMONT,BELGIUM
关键词
INFRARED SPECTROMETRY; CALIBRATION MODELS; SHENKS ALGORITHM;
D O I
10.1016/0003-2670(94)00237-1
中图分类号
O65 [分析化学];
学科分类号
070302 [分析化学]; 081704 [应用化学];
摘要
In this paper, transfer of calibration models between near-infrared spectrometric instruments using three different standardisation sets is described. The first set contains samples which are very similar to the agricultural samples from three different sets to be analysed, the second set contains generic standards, and the third one contains pure organic and inorganic chemicals. To test the accuracy of each standardisation, root mean square errors and correlation coefficients are computed before and after standardisation. To test the predictive ability, standard error of prediction for the three different prediction sets are also computed before and after standardisation. For standardisation, Shenk's algorithm is used: a description of this algorithm is given.
引用
收藏
页码:405 / 416
页数:12
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