SYNCHROTRON X-RAY ABSORPTION STUDIES ON THE 12-CROWN-4 AND 15-CROWN-5 COMPLEXES OF ANTIMONY(III) CHLORIDE

被引：7

作者：

BEAGLEY, B ^{[1
]}

机构：

[1] UNIV TRONDHEIM,DEPT CHEM,AVH,N-7055 DRAGVOLL,NORWAY

来源：

ACTA CHEMICA SCANDINAVICA | 1991年 / 45卷 / 04期

关键词：

D O I：

10.3891/acta.chem.scand.45-0349

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

The extended X-ray absorption fine structure spectrum of powdered SbCl3.12-crown-4 has been measured at room temperature using synchrotron radiation. With the aid of standard full-matrix least-squares fitting methods and SbCl3.15-crown-5 as a model complex for extracting the amplitude and phase parameters for the Sb-Cl, Sb-O and Sb-C bonds, it was possible to show that the data are consistent with a pyramidal geometry for SbCl3 that is complexed to the macrocycle through Sb-O bonds to all four oxygen atoms.

引用

收藏

页码：349 / 353

页数：5

相关论文

共 21 条

[1] DIBROMO(1,4-DIOXAN)TIN(II) - CRYSTAL-STRUCTURE [J].

ANDREWS, RH ;

DONALDSON, JD ;

HOUGH, E ;

NICHOLSON, DG .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1977, 33 (JAN15) :307-308

[2] MN(II)-I BONDS IN COMPLEXES IN SOLUTION AND CRYSTALLINE PHASES STRUCTURAL STUDIES BY EXAFS AND X-RAY CRYSTALLOGRAPHY [J].

BEAGLEY, B ;

MCAULIFFE, CA ;

PRITCHARD, RG ;

WHITE, EW .

ACTA CHEMICA SCANDINAVICA SERIES A-PHYSICAL AND INORGANIC CHEMISTRY, 1988, 42 (8-9) :544-553

[3] THE CRYSTAL-STRUCTURES OF ALUMINOSILICATE SODALITES - X-RAY-DIFFRACTION STUDIES AND COMPUTER MODELING [J].

BEAGLEY, B ;

HENDERSON, CMB ;

TAYLOR, D .

MINERALOGICAL MAGAZINE, 1982, 46 (341) :459-464

[4] COMPLEXES OF SOME CROWN ETHERS WITH TIN(II) IN METHANOL SOLUTION - SYNCHROTRON X-RAY ABSORPTION STUDIES ON THE 12-CROWN-4 AND 15-CROWN-5 COMPLEXES [J].

BEAGLEY, B ;

NICHOLSON, DG .

ACTA CHEMICA SCANDINAVICA, 1989, 43 (06) :527-531

[5]

BEAGLEY B, 1975, MOL STRUCTURE DIFFRA, V3, P52

[6]

BEAGLEY B, 1988, STEREOCHEMICAL APPLI, pCH13

[7] EMPIRICAL BOND-STRENGTH BOND-LENGTH CURVES FOR OXIDES [J].

BROWN, ID ;

SHANNON, RD .

ACTA CRYSTALLOGRAPHICA SECTION A, 1973, A 29 (MAY1) :266-282

[8] STEREOCHEMICAL ACTIVITY OF LONE PAIRS - THE CRYSTAL AND MOLECULAR-STRUCTURES OF THE SALTS OF CHLORO(1,4,7,10,13,16-HEXAOXACYCLO-OCTADECANE)TIN(II) - CALCULATION OF MACROCYCLIC CAVITY SIZE BY FORCE-FIELD METHODS [J].

DREW, MGB ;

NICHOLSON, DG .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1986, (08) :1543-1549

[9] STEREOCHEMICAL ACTIVITY OF LONE PAIRS - THE CRYSTAL AND MOLECULAR-STRUCTURE OF A COMPLEX OF 18-CROWN-6(1,4,7,10,13,16-HEXAOXACYCLOOCTADECANE) WITH BISMUTH(III) CHLORIDE [J].

DREW, MGB ;

NICHOLSON, DG ;

SYLTE, I ;

VASUDEVAN, A .

INORGANICA CHIMICA ACTA, 1990, 171 (01) :11-15

[10]

Greenwood NN, 1984, CHEM ELEMENTS