INITIATED TERT-BUTYL HYDROPEROXIDE-LOADED LOW-TEMPERATURE AUTOXIDATION OF ALKENES - ALTERNATIVE HYDROPEROXIDE SYNTHESES AND THE PREPARATION OF A COMPLETE SET OF REFERENCE MATERIALS

被引：10

作者：

COURTNEIDGE, JL

BUSH, M

LOH, LS

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1992年 / 12期

关键词：

D O I：

10.1039/p19920001539

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A complete set of characterization data for the allylic hydroperoxides prepared from 1 -methylcyclohexene and the isomeric 4-methyloct-4-enes is presented. The data relies upon the preparation of allylic hydroperoxides by tert-butyl hydroperoxide-loaded autoxidations, singlet-ene oxidations and nucleophilic substitution reactions. Appropriate allylic alcohols and relevant scission products have been prepared to support the assignments given.

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页码：1539 / 1548

页数：10

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