RAPID ISOMERIZATION OF ALLYLIC ALCOHOLS WITH IRIDIUM(I) AND RHODIUM(I) COMPLEXES AT AMBIENT TEMPERATURE

被引：19

作者：

Chin, Chong Shik ^{[1
]}

Park, Jeonghan ^{[1
]}

Kim, Choongil ^{[1
]}

Lee, Sun Yeoul ^{[1
]}

Shin, Jun Ho ^{[1
]}

Kim, Joong Bae ^{[1
]}

机构：

[1] Sogang Univ, Dept Chem, Seoul 121, South Korea

来源：

CATALYSIS LETTERS | 1988年 / 1卷 / 6-7期

关键词：

D O I：

10.1007/BF00766175

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Among allylic alcohols, but-3-en-2-ol is most rapidly isomerized to give butan-2-one in the presence of Ir(ClO4)(CO)(PPh3)(2) while 2-methylprop-2-en-l-ol most rapidly undergoes the isomerization to give 2-methylpropanal in the presence of Rh(ClO4)(CO)(PPh3)(2) at room temperature under hydrogen.

引用

页码：203 / 205

页数：3

共 14 条

[1]

Alper H., J ORG CHEM, V45, P2269

[2]

BAUDRY D, 1978, NOUV J CHIM, V2, P355

[3]

Chin C.S., J ORGANOMET IN PRESS

[4]

Dramico R., 1967, J ORG CHEM, V32, P2365