CHELATION CONTROL ASSOCIATED WITH ORGANOMETALLIC ADDITION-REACTIONS IN WATER - THE HIGH STEREOSELECTIVITY OFFERED BY ALPHA-HYDROXYL AND BETA-HYDROXYL SUBSTITUENTS OBVIATES THE NEED FOR PROTECTING GROUPS

被引：73

作者：

PAQUETTE, LA

MITZEL, TM

机构：

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 38期

关键词：

D O I：

10.1016/0040-4039(95)01439-o

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

High stereoselectivities have been observed for indium-promoted allylations of alpha- and beta-hydroxy aldehydes in aqueous media, with strong implication that chelate control can continue to operate in water.

引用

页码：6863 / 6866

页数：4

共 30 条

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