2 CRYSTALLINE POLYMORPHS OF CHLORO-[TRIS(2CYANOETHYL)PHOSPHINE]GOLD(I), [AUCL(C9H12N3P]

被引：13

作者：

FACKLER, JP

STAPLES, RJ

KHAN, MNI

WINPENNY, REP

机构：

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1994年 / 50卷

关键词：

D O I：

10.1107/S0108270193013472

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Polymorph (1) has Au-Cl and Au-P bond lengths of 2.295 (3) and 2.225 (3) angstrom, respectively, with a P-Au-Cl bond angle of 177.8 (1)-degrees. Polymorph (2) has Au-Cl and Au-P bond lengths of 2.315 (2) and 2.243 (2) angstrom, respectively, with a P-Au-Cl bond angle of 177.1 (1)-degrees. Polymorph (2) crystallizes with two of the C=N groups alongside the Au(I) center in the asymmetric unit.

引用

收藏

页码：1020 / 1023

页数：4

相关论文

共 10 条

[1]

ASSEFA Z, 1994, IN PRESS INORG CHEM

[2] CHLORO(TRIPHENYLPHOSPHINE)GOLD(I) [J].

BAENZIGER, NC ;

BENNETT, WE ;

SOBOROFF, DM .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1976, 32 (MAR15) :962-963

[3] CHLORO[TRIS(ORTHO-TOLYL)PHOSPHINE]GOLD(I) [J].

HARKER, CSW ;

TIEKINK, ERT .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1990, 46 :1546-1547

[4] CHLORO[TRIS(M-TOLYL)PHOSPHINE]GOLD(I) [J].

HARKER, CSW ;

TIEKINK, ERT .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1991, 47 :878-879

[5] SYNTHESES AND CHARACTERIZATION OF GOLD(I) AND PLATINUM(II) COMPLEXES CONTAINING TRIS(2-CYANOETHYL)PHOSPHINE - X-RAY CRYSTAL-STRUCTURES OF [(CEP)2AU]CL, CIS-(CEP)(ET2S)PTCL2, AND TRANS-(CEP)2PTCL2 [J].

KHAN, MNI ;

KING, C ;

FACKLER, JP ;

WINPENNY, REP .

INORGANIC CHEMISTRY, 1993, 32 (11) :2502-2505

[6] 2 CRYSTALLINE PHASES OF CHLOROTRIS(2-PYRIDYL)PHOSPHINEGOLD(I) [J].

LOCK, CJL ;

TURNER, MA .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1987, 43 :2096-2099

[7] STRUCTURES OF 2 GOLD(I) COMPLEXES WITH TRICYCLOHEXYLPHOSPHINE - [(CY3P)AUCL] AND [(CY3P)2AU]+.CL- [J].

MUIR, JA ;

MUIR, MM ;

PULGAR, LB ;

JONES, PG ;

SHELDRICK, GM .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1985, 41 (AUG) :1174-1176

[8] STRUCTURE OF CHLORO(DICYCLOHEXYLPHENYLPHOSPHINE)GOLD(I) [J].

MUIR, JA ;

CUADRADO, SI ;

MUIR, MM .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1991, 47 :1072-1074

[9]

SHELDRICK GM, 1986, SHELXTL USER MANUAL

[10] CHLORO(TRIETHYLPHOSPHINE)GOLD(I) [J].

TIEKINK, ERT .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1989, 45 :1233-1234