STUDIES IN GERMANIUM OXIDE SYSTEMS .4. PHASE EQUILIBRIA IN SYSTEM K20-GEO2

被引:38
作者
MURTHY, MK
LONG, L
IP, J
机构
[1] Department of Materials Chemistry, Ontario Research Foundation, Ontario, Sheridan Park
关键词
D O I
10.1111/j.1151-2916.1968.tb12640.x
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Phase relations in the binary system K2O‐GeO2 were determined by conventional quenching techniques. Three compounds, K2O.2GeO2, 3K2O.11GeO2, and K2O.7GeO2, exist in the composition range 65 to 100% GeOn. The compound 3K2O.1lGeO2 melts congruently at 1055°C, whereas K2O.2GeO2 and K2O.7GeO2 melt incongruently at 761° and 950°C, respectively. Thermal expansion data for the crystalline compounds are presented. The structure of potassium germanate glasses is discussed. Copyright © 1968, Wiley Blackwell. All rights reserved
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页码:661 / &
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