IR SPECTROSCOPIC STUDY OF ADSORBED SPECIES FORMED ON ELECTRODES DURING THE FE(CN)63-/4- CHARGE-TRANSFER REACTION

被引：33

作者：

NIWA, K ^{[1
]}

DOBLHOFER, K ^{[1
]}

机构：

[1] MAX PLANCK GESELL,FRITZ HABER INST,D-1000 BERLIN 33,FED REP GER

来源：

ELECTROCHIMICA ACTA | 1986年 / 31卷 / 04期

关键词：

ELECTROLYTES - GOLD AND ALLOYS - IONS - Adsorption - PLATINUM AND ALLOYS - SPECTROSCOPY; INFRARED; -; Applications;

D O I：

10.1016/0013-4686(86)80106-2

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Infrared reflection-adsorption spectra (IRAS) were taken from Au and Pt electrode surfaces which had been immersed from electrolytes containing the redox system Fe(CN)//6**3** minus **/**4** minus . The IRAS results show that the coverage of the electrodes with redox ions is smaller than has been suggested in the literature; strong specific adsorption of the redox ions was in no case detected. However, it is demonstrated that particularly in slightly acidic and in NH//4** plus containing electrolytes Prussian blue layers are formed on the electrodes.

引用

页码：439 / 443

页数：5

共 34 条

[1] DEPENDENCE OF RATE OF FE(CN)3-/6/FE(CN)4-/6 COUPLE ON IONIC-STRENGTH IN CONCENTRATED SOLUTIONS [J].

BINDRA, P ;

GERISCHER, H ;

PETER, LM .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1974, 57 (03) :435-438

[2] SINGLE-CRYSTAL STUDY OF PRUSSIAN BLUE - FE4[FE(CN)6]2, 14H2O [J].

BUSER, HJ ;

LUDI, A .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1972, (23) :1299-&

[3] KINETICS OF ELECTRON EXCHANGE BETWEEN HEXACYANOFERRATE(2) AND -(3) IONS [J].

CAMPION, RJ ;

DECK, CF ;

KING, P ;

WAHL, AC .

INORGANIC CHEMISTRY, 1967, 6 (04) :672-&

[4] ELECTROCHROMISM IN THE MIXED-VALENCE HEXACYANIDES .1. VOLTAMMETRIC AND SPECTRAL STUDIES OF THE OXIDATION AND REDUCTION OF THIN-FILMS OF PRUSSIAN BLUE [J].

ELLIS, D ;

ECKHOFF, M ;

NEFF, VD .

JOURNAL OF PHYSICAL CHEMISTRY, 1981, 85 (09) :1225-1231

[5] ELECTRODE CLEANING AND ANION EFFECTS ON KS FOR K3FE(CN)6 COUPLE [J].

GOLDSTEIN, EL ;

VANDEMARK, MR .

ELECTROCHIMICA ACTA, 1982, 27 (08) :1079-1085

[6] INFRARED STUDY OF ADSORBED MOLECULES ON METAL SURFACES BY REFLECTION TECHNIQUES [J].

GREENLER, RG .

JOURNAL OF CHEMICAL PHYSICS, 1966, 44 (01) :310-&

[7] THERMODYNAMIC ASPECTS OF POTASSIUM HEXACYANOFERRATE(3)-(2) SYSTEM .2. REDUCTION POTENTIAL [J].

HANANIA, GIH ;

IRVINE, DH ;

EATON, WA ;

GEORGE, P .

JOURNAL OF PHYSICAL CHEMISTRY, 1967, 71 (07) :2022-&

[8] ELECTRIC FIELDS PRODUCED BY PROPAGATION OF PLANE COHERENT ELECTROMAGNETIC RADIATION IN A STRATIFIED MEDIUM [J].

HANSEN, WN .

JOURNAL OF THE OPTICAL SOCIETY OF AMERICA, 1968, 58 (03) :380-&

[9] INFRARED REFLEXION-ABSORPTION MEASUREMENTS ON EMERSED GOLD ELECTRODES [J].

HOFMANN, O ;

DOBLHOFER, K ;

GERISCHER, H .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1984, 161 (02) :337-344

[10]

HOFMANN O, 1983, THESIS FU BERLIN

← 1 2 3 4 →