SYNTHESIS OF PHELLANPHOS, AN EFFICIENT CHIRAL 1,2-DIPHOSPHINE FOR ASYMMETRIC CATALYSIS

被引：30

作者：

LAUER, M ^{[1
]}

SAMUEL, O ^{[1
]}

KAGAN, HB ^{[1
]}

机构：

[1] UNIV PARIS 11,CNRS,SYNTHESE ASYMET LAB,LA 040255,F-91405 ORSAY,FRANCE

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 177卷 / 01期

关键词：

D O I：

10.1016/S0022-328X(00)92357-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A chiral 1,2-diphosphine was prepared in two steps from ()-α-phellandrene. This phosphine phellanphos gives a cationic rhodium complex (phellanphos-cyclooctadienerhodium hexafluorophosphate) which catalyses asymmetric reductions. N-Acetylphenylalanine and N-acetylalanine have been prepared in 94-95% enantiomeric excess. © 1979.

引用

页码：309 / 312

页数：4

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