OBSERVATION OF ACRYLONITRILE MOLECULAR ANION IN THE GAS-PHASE

被引：9

作者：

TSUKUDA, T

KONDOW, T

机构：

[1] Department of Chemistry, Faculty of Science, The University of Tokyo, Bunkyo-ku, Tokyo

来源：

CHEMICAL PHYSICS LETTERS | 1991年 / 185卷 / 5-6期

关键词：

D O I：

10.1016/0009-2614(91)80252-S

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The molecular anion of acrylonitrile was produced in the gas phase by collisional electron transfer from a high-Rydberg atom, Rg** (Rg = Kr or Ar), to an acrylonitrile or acrylonitrile-d1 molecule. The observed negative-ion mass spectra of m/z 53 or 54 indicate that both vertical and adiabatic electron affinities of the molecules are positive. The molecular anion of acrylonitrile was also produced by evaporative electron attachment to acrylonitrile clusters.

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页码：511 / 515

页数：5

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