ANALYSIS OF THE GENERALIZED STUECKELBERG METHOD OF NON-ADIABATIC TRANSITIONS

被引：9

作者：

BANDRAUK, AD ^{[1
]}

MILLER, WH ^{[1
]}

机构：

[1] UNIV CALIF BERKELEY,DEPT CHEM,BERKELEY,CA 94720

来源：

MOLECULAR PHYSICS | 1979年 / 38卷 / 06期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1080/00268977900102931

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The generalized Stueckelberg model of non-adiabatic transitions is applied to the linear curve crossing problem. It is shown that the theory can be analytically continued for all energies, thus reproducing the adiabatic asymptotic formulae derived by the Nikitin school for the Landau-Zener model. Comparisons are made with exact numerical calculations and excellent agreement is obtained in the adiabatic regime. The method is less accurate for low energies in the intermediate non-adiabatic coupling region. © 1979 Taylor & Francis Ltd.

引用

页码：1893 / 1907

页数：15

共 36 条

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Abramowitz M, 1965, HDB MATH TABLES

[2]

[Anonymous], 1932, HELV PHYS ACTA, DOI DOI 10.5169/SEALS-110177

[3] ANALYTIC PREDISSOCIATION LINEWIDTHS FROM SCATTERING THEORY [J].