ASYMMETRIC-SYNTHESIS OF A STERICALLY RIGID - BINAPHTHYL-BRIDGED CHIRAL METALLOCENE - ASYMMETRIC CATALYTIC EXPOXIDATION OF UNFUNCTIONALIZED ALKENES

被引：62

作者：

HALTERMAN, RL

RAMSEY, TM

机构：

[1] Department of Chemistry and Biochemistry, University of Oklahoma, Norman, Oklahoma 73019-0370

来源：

ORGANOMETALLICS | 1993年 / 12卷 / 08期

关键词：

D O I：

10.1021/om00032a003

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis of the first enantiomerically enriched C2-symmetrical bridged titanocene dichloride which incorporates homotopic cyclopentadienyl moieties is described, along with its application as an asymmetric epoxidation catalyst.

引用

页码：2879 / 2880

页数：2

共 26 条

[1] THE NONPLANAR STRUCTURE OF 2,2'-DILITHIO-1,1'-BINAPHTHYL - AN EXPERIMENTAL ESTIMATE OF THE LITHIUM-BRIDGING STABILIZATION ENERGY FOR A DILITHIOBIARYL [J].

BROWN, KJ ;

MURDOCH, JR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (25) :7843-7845

[2] SYNTHESIS OF OPTICALLY-ACTIVE 2,2'-DIHALO-1,1'-BINAPHTHYLS VIA STABLE DIAZONIUM SALTS [J].

BROWN, KJ ;

BERRY, MS ;

MURDOCH, JR .

JOURNAL OF ORGANIC CHEMISTRY, 1985, 50 (22) :4345-4349

[3] C2-SYMMETRICAL 2,2'-DIMETHYL-1,1'-BINAPHTHYL-BRIDGED ANSA-BIS(1-INDENYL)METAL COMPLEXES [J].

BURK, MJ ;

COLLETTI, SL ;

HALTERMAN, RL .

ORGANOMETALLICS, 1991, 10 (09) :2998-3000

[4] THE PREPARATION AND CATALYTIC APPLICATIONS OF SUPPORTED ZIRCONOCENE AND HAFNOCENE COMPLEXES [J].

CHANG, BH ;

GRUBBS, RH ;

BRUBAKER, CH .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1985, 280 (03) :365-376

[5] ENANTIOSELECTIVE CATALYTIC ISOMERIZATION OF AN UNFUNCTIONALIZED ACHIRAL ALKENE [J].

CHEN, ZL ;

HALTERMAN, RL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (06) :2276-2277

[6] ASYMMETRIC EPOXIDATION OF UNFUNCTIONALIZED ALKENES USING THE NEW C2-SYMMETRICAL 1,1'-BINAPHTHYL-2,2'-DIMETHYLENE-BRIDGED ANSA-BIS(1-INDENYL)TITANIUM DICHLORIDE CATALYST [J].

COLLETTI, SL ;

HALTERMAN, RL .

TETRAHEDRON LETTERS, 1992, 33 (08) :1005-1008

[7] STEREOSELECTIVITY IN THE SYNTHESIS OF TETRAMETHYLETHANO-BRIDGED 3,3'-DI-TERT-BUTYLTITANOCENE DICHLORIDE [J].

ERICKSON, MS ;

FRONCZEK, FR ;

MCLAUGHLIN, ML .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 415 (01) :75-85

[8]

Finn M. G., 1985, ASYMMETRIC SYNTHESIS, V5, P247

[9] CATALYTIC ASYMMETRIC EPOXIDATION AND KINETIC RESOLUTION - MODIFIED PROCEDURES INCLUDING INSITU DERIVATIZATION [J].

GAO, Y ;

HANSON, RM ;

KLUNDER, JM ;

KO, SY ;

MASAMUNE, H ;

SHARPLESS, KB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (19) :5765-5780

[10] RESPONSE OF ACIDITY AND MAGNETIC-RESONANCE PROPERTIES TO ARYL SUBSTITUTION IN CARBON ACIDS AND DERIVED CARBANIONS - 2-ARYLINDENES AND 3-ARYLINDENES [J].

GREIFENSTEIN, LG ;

LAMBERT, JB ;

NIENHUIS, RJ ;

FRIED, HE ;

PAGANI, GA .

JOURNAL OF ORGANIC CHEMISTRY, 1981, 46 (25) :5125-5132

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